Characteristics of Polycarbonate Soft Segment-Based Thermoplastic Polyurethane

نویسندگان

چکیده

The pre-experiment of the present study revealed that polyurethane (PU) synthesized using poly (hexamethylene carbonate) glycol (PHC) has high melt viscosity and is difficult to process. Therefore, (trimethylene (PTC) was employed synthesize a PU product with low viscosity. First, four types thermoplastic (TPU) were formed through one-step solvent-free synthesis. TPU presented in format “TPU-X-Y,” X representing polyol (PTC or PHC, around 1000 molecular weight) Y chain extender (1,3-propane diol [PDO] 1,4-butane [BDO]) used. fixed molar ratio (isocyanate):(polyol):(chain extender) = 2:1:1 compared. results indicated entanglement often occurred among long carbon chains PHC. property PTC, namely converting polarity into reverse temperatures, resolve PHC series, which causes processing difficulties. TPU-PTC-PDO exhibited favorable arrangements. Given its polarity, outstanding tensile properties (strength at break: 41.10 ± 10.78 MPa; 100% modulus 6.73 0.12 MPa), making lower temperatures (180 190 °C) feasible. With inclusion polycarbonate exhibits advantages suitable for wide range applications.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Synthesis of bio-based thermoplastic polyurethane elastomers containing isosorbide and polycarbonate diol and their biocompatible properties.

A new family of highly elastic polyurethanes (PUs) partially based on renewable isosorbide were prepared by reacting hexamethylene diisocyanate with a various ratios of isosorbide and polycarbonate diol 2000 (PCD) via a one-step bulk condensation polymerization without catalyst. The influence of the isorsorbide/PCD ratio on the properties of the PU was evaluated. The successful synthesis of the...

متن کامل

Control of Mechanical Properties of Thermoplastic Polyurethane Elastomers by Restriction of Crystallization of Soft Segment

Mechanical properties of thermoplastic polyurethane elastomers based on either polyether or polycarbonate (PC)-glycols, 4,4'-dipheylmethane diisocyanate (1,1'-methylenebis(4-isocyanatobenzene)), 1,4-butanediol, were controlled by restriction of crystallization of polymer glycols. For the polyether glycol based-polyurethane elastomers (PUEs), poly(oxytetramethylene) glycol (PTMG), and PTMG incor...

متن کامل

Stress-Strain Behavior of Thermoplastic Polyurethane

The large strain nonlinear stress-strain behavior of thermoplastic polyurethanes (TPUs) exhibits strong hysteresis, rate dependence and softening. Thermoplastic polyurethanes are copolymers composed of hard and soft segments. The hard and soft segments phase separate to form a microstructure of hard and soft domains typically on a length scale of a few tens of nanometers. Studies have revealed ...

متن کامل

Effect of soft segment and clay volume fraction on rate dependent damping of polyurethane and polyurethane-clay nanocomposites

Amorphous polymers have been extensively used for energy dissipative applications due to their relatively low density and controllable rate dependent damping. In general, molecular mobility depends on the rate of applied loading and the ambient temperature, and results in a wide variety of mechanical properties. The variation in the macromolecular chain dynamics can be obtained by altering the ...

متن کامل

Mechanical Properties of Nonwoven Reinforced Thermoplastic Polyurethane Composites

Reinforcement of flexible fibre reinforced plastic (FRP) composites with standard textile fibres is a potential low cost solution to less critical loading applications. The mechanical behaviour of FRPs based on mechanically bonded nonwoven preforms composed of either low or high modulus fibres in a thermoplastic polyurethane (TPU) matrix were compared following compression moulding. Nonwoven pr...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Applied sciences

سال: 2021

ISSN: ['2076-3417']

DOI: https://doi.org/10.3390/app11125359